Hey @daodio2,
This is technically possible, as the WIE is Win-PE with some scripts, but Win-PE out of the box does not support Wi-Fi (so you'll have to use some online guides to hack it in), and you'll probably have to modify the WIE scripts to enable the WLAN component to obtain an IP. From there, if you're using standard imaging over http, it will most likely be super slow and fragile. If you're using SMB, it would probably be better, but still not great.
TLDR: Is it possible? Yes, look online for guides to add WLAN to Win-PE and modify the scripts once you get it working. Do you wanna do it? Probably not.
I looked into this for a while and decided against it. We have old switches that I can use for mass imaging if needed.